<?xml version="1.0" encoding="UTF-8"?>

<!--XBRL Document Created with the Workiva Platform-->
<!--Copyright 2025 Workiva-->
<!--r:a3ed5e44-6091-4a40-8aeb-98f0ba064838,g:5a862183-8e0e-4634-8ed7-391dc9ade73a-->
<link:linkbase xmlns:link="http://www.xbrl.org/2003/linkbase" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.xbrl.org/2003/linkbase http://www.xbrl.org/2003/xbrl-linkbase-2003-12-31.xsd">
  <link:roleRef roleURI="http://opalfuels.com/role/Cover" xlink:type="simple" xlink:href="opal-20250424.xsd#Cover"/>
  <link:presentationLink xlink:role="http://opalfuels.com/role/Cover" xlink:type="extended">
    <link:loc xlink:type="locator" xlink:label="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_CoverAbstract"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_DocumentType_865a9250-7b0e-46cd-b416-818f25d3b76d" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_DocumentType"/>
    <link:presentationArc order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_DocumentType_865a9250-7b0e-46cd-b416-818f25d3b76d" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_DocumentPeriodEndDate_092b1fc0-f95f-45a2-82c2-5e35ff929bc9" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_DocumentPeriodEndDate"/>
    <link:presentationArc order="2" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_DocumentPeriodEndDate_092b1fc0-f95f-45a2-82c2-5e35ff929bc9" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityRegistrantName_52756e8c-5b61-4017-b66e-592ccf5bff16" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityRegistrantName"/>
    <link:presentationArc order="3" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_EntityRegistrantName_52756e8c-5b61-4017-b66e-592ccf5bff16" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityIncorporationStateCountryCode_1eb54579-44ce-4d0d-b148-36681f38cb1c" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityIncorporationStateCountryCode"/>
    <link:presentationArc order="4" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_EntityIncorporationStateCountryCode_1eb54579-44ce-4d0d-b148-36681f38cb1c" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityFileNumber_ff852e2d-f849-46e8-9886-fe25ac2b1f9b" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityFileNumber"/>
    <link:presentationArc order="5" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_EntityFileNumber_ff852e2d-f849-46e8-9886-fe25ac2b1f9b" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityTaxIdentificationNumber_0e09abad-23b1-479a-939a-0587a82110df" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityTaxIdentificationNumber"/>
    <link:presentationArc order="6" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_EntityTaxIdentificationNumber_0e09abad-23b1-479a-939a-0587a82110df" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityAddressAddressLine1_f8e4f509-5b0c-4780-b493-2aa01bc895e5" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityAddressAddressLine1"/>
    <link:presentationArc order="7" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_EntityAddressAddressLine1_f8e4f509-5b0c-4780-b493-2aa01bc895e5" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityAddressAddressLine2_6602e7e3-8ca0-4990-9203-cb3ae1c71a76" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityAddressAddressLine2"/>
    <link:presentationArc order="8" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_EntityAddressAddressLine2_6602e7e3-8ca0-4990-9203-cb3ae1c71a76" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityAddressCityOrTown_24e0f881-f7ef-471d-94b5-77909ed1549d" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityAddressCityOrTown"/>
    <link:presentationArc order="9" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_EntityAddressCityOrTown_24e0f881-f7ef-471d-94b5-77909ed1549d" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityAddressStateOrProvince_a29ef27a-0ce7-4794-9299-0edf518ea874" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityAddressStateOrProvince"/>
    <link:presentationArc order="10" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_EntityAddressStateOrProvince_a29ef27a-0ce7-4794-9299-0edf518ea874" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityAddressPostalZipCode_6cdccf18-0646-4af9-b9aa-beee651a1778" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityAddressPostalZipCode"/>
    <link:presentationArc order="11" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_EntityAddressPostalZipCode_6cdccf18-0646-4af9-b9aa-beee651a1778" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_CityAreaCode_fd2ba7d3-f881-4aea-b26e-c53b58be0645" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_CityAreaCode"/>
    <link:presentationArc order="12" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_CityAreaCode_fd2ba7d3-f881-4aea-b26e-c53b58be0645" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_LocalPhoneNumber_ecd1d7ba-fc84-4a38-93f9-3f3c3def2c3d" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_LocalPhoneNumber"/>
    <link:presentationArc order="13" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_LocalPhoneNumber_ecd1d7ba-fc84-4a38-93f9-3f3c3def2c3d" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_WrittenCommunications_335177d8-ef1e-4793-a2b7-8fd9e08934ed" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_WrittenCommunications"/>
    <link:presentationArc order="14" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_WrittenCommunications_335177d8-ef1e-4793-a2b7-8fd9e08934ed" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_SolicitingMaterial_81c13b80-26b7-449f-8840-31db6993ffc5" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_SolicitingMaterial"/>
    <link:presentationArc order="15" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_SolicitingMaterial_81c13b80-26b7-449f-8840-31db6993ffc5" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_PreCommencementTenderOffer_fa9ac088-8212-4269-bec7-8b6fb9d1d6e9" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_PreCommencementTenderOffer"/>
    <link:presentationArc order="16" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_PreCommencementTenderOffer_fa9ac088-8212-4269-bec7-8b6fb9d1d6e9" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_PreCommencementIssuerTenderOffer_2f17abd9-6536-4cf3-af38-b7852ebb56bf" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_PreCommencementIssuerTenderOffer"/>
    <link:presentationArc order="17" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_PreCommencementIssuerTenderOffer_2f17abd9-6536-4cf3-af38-b7852ebb56bf" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_Security12bTitle_69e97cf3-b9ca-4fc9-a439-71122421c2d3" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_Security12bTitle"/>
    <link:presentationArc order="18" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_Security12bTitle_69e97cf3-b9ca-4fc9-a439-71122421c2d3" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_TradingSymbol_b9e4a807-8124-4b9f-a7a1-5083c70059be" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_TradingSymbol"/>
    <link:presentationArc order="19" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_TradingSymbol_b9e4a807-8124-4b9f-a7a1-5083c70059be" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_SecurityExchangeName_a7a6056c-5903-4690-8f81-cee678fce6f6" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_SecurityExchangeName"/>
    <link:presentationArc order="20" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_SecurityExchangeName_a7a6056c-5903-4690-8f81-cee678fce6f6" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityEmergingGrowthCompany_aff0d354-3be9-4f85-8df9-923c4eb17231" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityEmergingGrowthCompany"/>
    <link:presentationArc order="21" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_EntityEmergingGrowthCompany_aff0d354-3be9-4f85-8df9-923c4eb17231" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityExTransitionPeriod_a48dd9f5-a041-4ac8-9057-1659d1a4ef41" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityExTransitionPeriod"/>
    <link:presentationArc order="22" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_EntityExTransitionPeriod_a48dd9f5-a041-4ac8-9057-1659d1a4ef41" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityCentralIndexKey_78bd2bc8-044d-427a-8081-d3b288fed165" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityCentralIndexKey"/>
    <link:presentationArc order="23" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_EntityCentralIndexKey_78bd2bc8-044d-427a-8081-d3b288fed165" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_AmendmentFlag_918d30ed-36aa-4360-9c4b-2607e7a0c79e" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_AmendmentFlag"/>
    <link:presentationArc order="24" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_faf8119d-0e64-4168-b283-7a03b813eaaf" xlink:to="loc_dei_AmendmentFlag_918d30ed-36aa-4360-9c4b-2607e7a0c79e" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
  </link:presentationLink>
</link:linkbase>
