<?xml version="1.0" encoding="UTF-8"?>

<!--XBRL Document Created with the Workiva Platform-->
<!--Copyright 2025 Workiva-->
<!--r:caa5dd83-cf97-4dc9-8c5a-913cc517d822,g:66e6c78e-ab1c-42c3-825f-42a3b67c67d7-->
<link:linkbase xmlns:link="http://www.xbrl.org/2003/linkbase" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.xbrl.org/2003/linkbase http://www.xbrl.org/2003/xbrl-linkbase-2003-12-31.xsd">
  <link:roleRef roleURI="http://opalfuels.com/role/Cover" xlink:type="simple" xlink:href="opal-20250508.xsd#Cover"/>
  <link:presentationLink xlink:role="http://opalfuels.com/role/Cover" xlink:type="extended">
    <link:loc xlink:type="locator" xlink:label="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_CoverAbstract"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_DocumentType_e0eaac78-b03e-4db4-886d-110610cc5328" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_DocumentType"/>
    <link:presentationArc order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_DocumentType_e0eaac78-b03e-4db4-886d-110610cc5328" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_DocumentPeriodEndDate_dc96c18e-68e9-443b-8c21-077cc6ee4c92" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_DocumentPeriodEndDate"/>
    <link:presentationArc order="2" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_DocumentPeriodEndDate_dc96c18e-68e9-443b-8c21-077cc6ee4c92" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityRegistrantName_a2bfa95b-20e2-4f8d-9009-6cb245beda95" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityRegistrantName"/>
    <link:presentationArc order="3" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_EntityRegistrantName_a2bfa95b-20e2-4f8d-9009-6cb245beda95" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityIncorporationStateCountryCode_2c5a95b3-44f7-424c-a081-78b72b281294" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityIncorporationStateCountryCode"/>
    <link:presentationArc order="4" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_EntityIncorporationStateCountryCode_2c5a95b3-44f7-424c-a081-78b72b281294" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityFileNumber_07df4094-5482-437c-8606-1ed50898afc0" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityFileNumber"/>
    <link:presentationArc order="5" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_EntityFileNumber_07df4094-5482-437c-8606-1ed50898afc0" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityTaxIdentificationNumber_96b729b9-b51e-43d4-ada8-fcd57dca22e1" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityTaxIdentificationNumber"/>
    <link:presentationArc order="6" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_EntityTaxIdentificationNumber_96b729b9-b51e-43d4-ada8-fcd57dca22e1" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityAddressAddressLine1_8e87f733-8841-4496-b356-a7d03f8974f5" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityAddressAddressLine1"/>
    <link:presentationArc order="7" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_EntityAddressAddressLine1_8e87f733-8841-4496-b356-a7d03f8974f5" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityAddressAddressLine2_348b5ce0-62c3-4215-aabe-60ec9b4114e0" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityAddressAddressLine2"/>
    <link:presentationArc order="8" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_EntityAddressAddressLine2_348b5ce0-62c3-4215-aabe-60ec9b4114e0" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityAddressCityOrTown_1ebdd5bc-c39d-4117-96cd-e6a8add9b0c0" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityAddressCityOrTown"/>
    <link:presentationArc order="9" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_EntityAddressCityOrTown_1ebdd5bc-c39d-4117-96cd-e6a8add9b0c0" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityAddressStateOrProvince_5076ec59-c2c7-41b2-8652-a4a207a6ee73" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityAddressStateOrProvince"/>
    <link:presentationArc order="10" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_EntityAddressStateOrProvince_5076ec59-c2c7-41b2-8652-a4a207a6ee73" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityAddressPostalZipCode_6dd0b6a9-08dd-40cf-9718-516de1645583" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityAddressPostalZipCode"/>
    <link:presentationArc order="11" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_EntityAddressPostalZipCode_6dd0b6a9-08dd-40cf-9718-516de1645583" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_CityAreaCode_586bc364-f70b-4a6d-aece-9eda0e87e90c" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_CityAreaCode"/>
    <link:presentationArc order="12" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_CityAreaCode_586bc364-f70b-4a6d-aece-9eda0e87e90c" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_LocalPhoneNumber_bcdbd99b-87f0-4064-b147-d80d18e550a6" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_LocalPhoneNumber"/>
    <link:presentationArc order="13" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_LocalPhoneNumber_bcdbd99b-87f0-4064-b147-d80d18e550a6" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_WrittenCommunications_9f78cda5-6a9a-4661-908f-980a2f294a51" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_WrittenCommunications"/>
    <link:presentationArc order="14" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_WrittenCommunications_9f78cda5-6a9a-4661-908f-980a2f294a51" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_SolicitingMaterial_a23f625d-8c0c-4f05-8da9-ffc40f675210" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_SolicitingMaterial"/>
    <link:presentationArc order="15" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_SolicitingMaterial_a23f625d-8c0c-4f05-8da9-ffc40f675210" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_PreCommencementTenderOffer_39d77af7-c2e0-4bf9-b5bf-690b9da4c9fc" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_PreCommencementTenderOffer"/>
    <link:presentationArc order="16" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_PreCommencementTenderOffer_39d77af7-c2e0-4bf9-b5bf-690b9da4c9fc" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_PreCommencementIssuerTenderOffer_1e1b2b12-f248-4e4f-a82c-fedfd480d4be" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_PreCommencementIssuerTenderOffer"/>
    <link:presentationArc order="17" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_PreCommencementIssuerTenderOffer_1e1b2b12-f248-4e4f-a82c-fedfd480d4be" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_Security12bTitle_bf293ada-3a89-4e37-8b64-20728fba3384" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_Security12bTitle"/>
    <link:presentationArc order="18" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_Security12bTitle_bf293ada-3a89-4e37-8b64-20728fba3384" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_TradingSymbol_d0fecaf2-915f-4a38-a3b7-4decc92259c8" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_TradingSymbol"/>
    <link:presentationArc order="19" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_TradingSymbol_d0fecaf2-915f-4a38-a3b7-4decc92259c8" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_SecurityExchangeName_a7263974-9a1d-4ee0-bac5-181fb215b0ec" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_SecurityExchangeName"/>
    <link:presentationArc order="20" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_SecurityExchangeName_a7263974-9a1d-4ee0-bac5-181fb215b0ec" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityEmergingGrowthCompany_4b146098-9c79-4e27-9fdf-ae07cd37a3ba" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityEmergingGrowthCompany"/>
    <link:presentationArc order="21" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_EntityEmergingGrowthCompany_4b146098-9c79-4e27-9fdf-ae07cd37a3ba" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityExTransitionPeriod_ec1d64b0-c7e4-4896-9c88-9976b60e12b8" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityExTransitionPeriod"/>
    <link:presentationArc order="22" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_EntityExTransitionPeriod_ec1d64b0-c7e4-4896-9c88-9976b60e12b8" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_EntityCentralIndexKey_08f6cd7b-178a-49a2-8843-a8a74f6af765" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_EntityCentralIndexKey"/>
    <link:presentationArc order="23" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_EntityCentralIndexKey_08f6cd7b-178a-49a2-8843-a8a74f6af765" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
    <link:loc xlink:type="locator" xlink:label="loc_dei_AmendmentFlag_3eed689a-3c1c-4f0a-a35d-dff4639cb4c5" xlink:href="https://xbrl.sec.gov/dei/2024/dei-2024.xsd#dei_AmendmentFlag"/>
    <link:presentationArc order="24" xlink:arcrole="http://www.xbrl.org/2003/arcrole/parent-child" xlink:from="loc_dei_CoverAbstract_8a8de021-bca3-4c79-bfc6-5515a9a4ed0b" xlink:to="loc_dei_AmendmentFlag_3eed689a-3c1c-4f0a-a35d-dff4639cb4c5" xlink:type="arc" preferredLabel="http://www.xbrl.org/2003/role/terseLabel"/>
  </link:presentationLink>
</link:linkbase>
